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Total synthesis of (+)-phomopsolide B

Prasad, Kavirayani R and Gutala, Phaneendra (2012) Total synthesis of (+)-phomopsolide B. In: TETRAHEDRON, 68 (36). pp. 7489-7493.

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Official URL: http://dx.doi.org/10.1016/j.tet.2012.06.002


An enantiospecific total synthesis of polyhydroxy delta-pyrone natural product phomopsolide B is accomplished. The main feature of the synthesis is the installation of the required E-olefin by Horner-Emmons-Wordsworth reaction and the formation of the lactone involving Still-Gennari olefination followed by lactonization. (C) 2012 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elseier Science
Keywords: Phomopsolide B; Polyhydroxy lactone; delta-Pyrone
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: review EPrints Reviewer
Date Deposited: 17 Dec 2012 07:41
Last Modified: 17 Dec 2012 07:41
URI: http://eprints.iisc.ac.in/id/eprint/45161

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