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Vijay, T and Anilkumar, HG and Yathirajan, HS and Narasimhamurthy, T and Rathore, RS (2005) 5-Chlorocarbonyl-10,11-dihydro-5h-dibenz[b,f]azepine. In: Acta Crystallographica Section E: Structure Reports Online, 61 . o3718-o3720.

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In the title compound, $C_{15}H_{12}ClNO$, the central seven-membered azepine ring adopts a bent conformation, intermediate between the boat and chair forms. The overall structure of the molecule is similar to a butterfly shape, which is commonly observed for carbamazepine analogues. The planes through the benzene rings on either side of the azepine ring intersect at an angle of $59.0 (1)^o$. The molecular assembly is primarily stabilized by aromatic \pi-\pi interactions.

Item Type: Journal Article
Publication: Acta Crystallographica Section E: Structure Reports Online
Publisher: Blackwell Publishing
Additional Information: Copyright for this article belongs to Blackwell Publishing.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 24 Jan 2006
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ac.in/id/eprint/4485

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