Dikundwar, Amol G and Row, Tayur Guru N (2012) Evidence for the ``Amphoteric'' Nature of Fluorine in Halogen Bonds: An Instance of Cl center dot center dot center dot F Contact. In: Crystal Growth & Design, 12 (4). pp. 1713-1716.
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Official URL: http://pubs.acs.org/doi/abs/10.1021/cg3002477
Abstract
This study presents unambiguous experimental evidence in support of the highly debated ``halogen bond donor'' character of organic fluorine. Two examples of intermolecular Cl center dot center dot center dot F contacts, with F-atom as halogen bond acceptor and donor, have been analyzed by in situ cryocrystallography and theoretical charge density studies.
Item Type: | Journal Article |
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Additional Information: | Copyright of this article is belongs to American Chemical Society. |
Keywords: | CHARGE-DENSITY ANALYSIS;X-RAY;INTERMOLECULAR INTERACTIONS; CRYSTAL-STRUCTURE;ORGANIC FLUORINE;PACKING;GEOMETRY;FORCES |
Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
Depositing User: | review EPrints Reviewer |
Date Deposited: | 14 Aug 2012 05:35 |
Last Modified: | 14 Aug 2012 05:36 |
URI: | http://eprints.iisc.ac.in/id/eprint/44495 |
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