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Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one

Srikrishna, A and Gowri, V (2012) Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one. In: Tetrahedron, 68 (14). pp. 3046-3055.

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Official URL: http://dx.doi.org/10.1016/j.tet.2012.02.018


Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin. (C) 2012 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article is belongs to Elsevier Science.
Keywords: Crinipellins;Tetraquinanes;Intramolecular rhodium carbenoid CH insertion;Enantiospecific synthesis;Campholenaldehyde; Intramolecular Michael addition
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: review EPrints Reviewer
Date Deposited: 23 Aug 2012 07:37
Last Modified: 23 Aug 2012 07:39
URI: http://eprints.iisc.ac.in/id/eprint/44469

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