Cubane ${Cu^{II}_4}$ Cluster as a Precursor for the Preparation of a Mixed-Valent ${Cu^{II}_{12}Cu^{I}_2}$ Core

Mukherjee, Arindam and Nethaji, Munirathinam and Chakravarty, Akhil R (2004) Cubane ${Cu^{II}_4}$ Cluster as a Precursor for the Preparation of a Mixed-Valent ${Cu^{II}_{12}Cu^{I}_2}$ Core. In: Angewandte Chemie International Edition, 43 (1). pp. 87-90.

Preview

PDF page93.pdf Download (159kB)

Abstract

Current interests in the chemistry of high-nuclearity transition- metal complexes draw from their utility in the emerging science of nanomaterials,[1] as models for the multimetal active sites of metal-storage proteins,[2] and as single molecule magnets (SMMs).[3,4] In addition, such super-sized molecules often show a variety of supramolecular interactions.[5] The "self-assembly" process of generating a high-nuclearity cluster from a mono- or dimeric precursor generally involves low-dentate organic ligands.

Item Type:	Journal Article
Publication:	Angewandte Chemie International Edition
Publisher:	WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information:	The copyright belongs to WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	08 Dec 2005
Last Modified:	19 Sep 2010 04:21
URI:	http://eprints.iisc.ac.in/id/eprint/4306

Actions (login required)

View Item