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Enantiospecific synthesis of angular triquinanes

Srikrishna, Adusumilli and Gowni, Vijayendran (2011) Enantiospecific synthesis of angular triquinanes. In: Tetrahedron: Asymmetry, 22 (14-15). pp. 1553-1559.

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Official URL: http://dx.doi.org/10.1016/j.tetasy.2011.08.016


The enantiospecific synthesis of angular triquinanes has been developed starting from the readily available (S)-campholenaldehyde. Two alternate strategies have been used, one employing a Johnson's orthoester Claisen rearrangement followed by an intramolecular cyclopropanation and regioselective cyclopropane ring cleavage, and a second one based on a RCM reaction. (C) 2011 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 23 Dec 2011 11:47
Last Modified: 23 Dec 2011 11:47
URI: http://eprints.iisc.ac.in/id/eprint/42852

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