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Solubility and activity of oxygen in liquid manganese

Jacob, KT (1981) Solubility and activity of oxygen in liquid manganese. In: Journal of the Minerals Metals & Materials Society, 12 (4). pp. 675-678.

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Abstract

The oxygen concentration of liquid manganese in equilibrium with MnAl2+2xO4+3x and α−Al2O3 has been determined in the temperature range 1520 to 1875 K. The oxygen content of quenched samples, wrapped in oxygen-free nickel foil, was determined by an inert gas fusion technique. The results are combined with accurate data now available on the Gibbs energies of formation of MnO and Al2O3−saturated MnAl2+2xO4+3x to derive the oxygen content of liquid manganese in equilibrium with MnO and the Gibbs energy of solution of diatomic oxygen gas in liquid manganese. The enthalpy and entropy of solution of oxygen in manganese are compared with similar data on other metal-oxygen systems.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to The Minerals, Metals & Materials Society.
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Depositing User: Ms V Mangala
Date Deposited: 05 Dec 2011 06:25
Last Modified: 05 Dec 2011 06:25
URI: http://eprints.iisc.ac.in/id/eprint/42552

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