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Microscopic modelling of adsorption and the generalised surface layer hypothesis

Sangaranarayanan, MV and Rangarajan, SK (1981) Microscopic modelling of adsorption and the generalised surface layer hypothesis. In: Canadian Journal of Chemistry / Revue Canadienne de Chimie, 59 (13). pp. 2072-2079.

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Abstract

Two- and three-state models for the adsorption of organic compounds at the electrode/electrolyte interface are proposed. Different size requirements, if any, for the neutral molecule and the adsorbing solvent are also considered. It is shown how the empirical, generalised surface layer (GSL) relationship (between the potential difference and the electrode charge) formulated by Damaskin et al. can be understood at the molecular level.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to NRC Research Press.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Ms Mary Ranjeetha
Date Deposited: 05 Nov 2011 07:28
Last Modified: 05 Nov 2011 07:28
URI: http://eprints.iisc.ac.in/id/eprint/41179

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