Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (-)-cucumin H

Srikrishna, A and Dethe, Dattatraya H (2003) Enantiospecific first total synthesis and assignment of absolute configuration of the sesquiterpene (-)-cucumin H. In: Organic Letters, 5 (13). pp. 2295-2298.

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Abstract

The first total synthesis of the sesquiterpene (-)-cucumin H, a linear triquinane isolated from Macrocystidia cucumis, has been accomplished starting from (R)-limonene employing two different cyclopentannulation methodologies, which in addition to confirming the structure also established the absolute configuration of the natural product.

Item Type:	Journal Article
Publication:	Organic Letters
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	29 Aug 2011 08:10
Last Modified:	29 Aug 2011 08:10
URI:	http://eprints.iisc.ac.in/id/eprint/40084

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