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Chiral synthons from carvone. Part 53. First enantiospecific synthesis of (-)-9-pupukeanone

Srikrishna, A and Kumar, Ravi P (2002) Chiral synthons from carvone. Part 53. First enantiospecific synthesis of (-)-9-pupukeanone. In: Tetrahedron Letters, 43 (6). pp. 1109-1111.

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Official URL: http://dx.doi.org/10.1016/S0040-4039(01)02336-X

Abstract

The first enantiospecific total synthesis of (-)-9-pupukeanone, starting from (R)-carvone employing a combination of Michael-Michael reaction and an intramolecular rhodium carbenoid C H insertion reaction as key steps, is described. (C) 2002 Elsevier Science Ltd. All rights reserved.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 22 Jul 2011 09:52
Last Modified: 22 Jul 2011 09:52
URI: http://eprints.iisc.ac.in/id/eprint/39047

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