Sureshkumar, Devarajulu and Koutha, Srinivasa Murthy and Chandrasekaran, Srinivasan (2005) Chemistry of Tetrathiomolybdate: Aziridine Ring Opening Reactions and Facile Synthesis of Interesting Sulfur Heterocycles. In: Journal of The American Chemical Society, 127 (37). pp. 12760-12761.
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Benzyltriethylammonium tetrathiomolybdate, $[BnEt_3N]_2MoS_4$, has been used successfully to effect ring opening of aziridines in a regiospecific and stereospecific manner under mild reaction conditions without the use of Lewis acid catalyst. Utility of this reagent in tandem and multistep processes in a one-pot operation for the synthesis of various novel sulfur heterocycles in very good yield is also reported.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of The American Chemical Society |
| Publisher: | American Chemical Society |
| Additional Information: | The copyright for this article belongs to American chemical Society. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 07 Oct 2005 |
| Last Modified: | 27 Aug 2008 11:30 |
| URI: | http://eprints.iisc.ac.in/id/eprint/3790 |
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