Srikrishna, A and Satyanarayana, G (2005) A formal total synthesis of $(\pm)$-9-isocyanoneopupukeanane. In: Tetrahedron, 61 (37). pp. 8855-8859.
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Abstract
A formal total synthesis of the marine sesquiterpene $(\pm)$-9-isocyanoneopupukeanane, starting from the readily available monoterpene carvone has been accomplished employing a combination of intermolecular Michael addition-intramolecular Michael addition reaction and an intramolecular rhodium carbenoid C-H insertion reaction as key steps, and identifying the isopropenyl group as a masked hydroxygroup.
Item Type: | Journal Article |
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Publication: | Tetrahedron |
Publisher: | Pergamon-Elsevier Science Ltd |
Additional Information: | Copyright for this article belongs to Elsevier. |
Keywords: | Marine sesquiterpenes;Neopupukeanane;Double Michael reaction;Rhodium CH insertion reaction |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 27 May 2006 |
Last Modified: | 19 Sep 2010 04:20 |
URI: | http://eprints.iisc.ac.in/id/eprint/3768 |
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