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Bi2W1–xCuxO6–x(0.7[less-than-or-eq]x[less-than-or-eq]0.8): a new oxide-ion conductor

Sharma, V and Shukla, AK and Gopalakrishnan, J (1994) Bi2W1–xCuxO6–x(0.7[less-than-or-eq]x[less-than-or-eq]0.8): a new oxide-ion conductor. In: Journal of materials chemistry, 4 (5). pp. 703-705.

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Anion-deficient Aurivillius phases of the general formula, Bi2Wi-xCuxO6-2x, possessing orthorhombic/tetragonal Bi2WO6-like structures, have been synthesized by quenching the oxide melts. The tetragonal phase stabilized for the compositions 0.7 less-than-or-equal-to x less-than-or-equal-to 0.8 is a good oxide-ion conductor in the temperature range 500-900 K, the x = 0.7 composition exhibiting the highest conductivity in the series.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal society of chemistry
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Ms V Mangala
Date Deposited: 25 Mar 2011 09:16
Last Modified: 25 Mar 2011 09:16
URI: http://eprints.iisc.ac.in/id/eprint/36266

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