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An electron-spin-resonance study of MN2+ doped calcium hydrazine carboxylate monohydrate

Gawad, MMA and Mahesh, GV and Patil, KC and Bhat, SV (1994) An electron-spin-resonance study of MN2+ doped calcium hydrazine carboxylate monohydrate. In: Bulletin of Materials Science, 17 (6). pp. 1131-1141.

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Single crystals of calcium hydrazine carboxylate, monohydrate have been studied by ESR of Mn2+ doped in the calcium sites. X-band ESR indicated a large crystal field splitting necessitating experiments at Q band. The analysis shows two magnetically inequivalent (but chemically equivalent) sites with g(xx) = 2.0042+/-0.0038, g(yy) = 2.0076 +/-00029, g(zz) =2.0314+/-0.001, A(zz) = 0.0099+/-0.0002 cm(-1), A(xx) = 0.0099+/-0.0002 cm(-1), A(yy) = 0.0082+/-0.0002cm(-1), D = 3/2D(zz) = 0.0558+/-0.0006cm(-1), and E = 1/2(D-xx-D-yy) = 0.0127+/-0.0002 cm(-1).One of the principal components of the crystal field, (D-zz), is found to be along the Ca<->Ca direction in the structure and a second one, (D-xx), along the perpendicular to the plane of the triangle formed by three neighbouring calciums. The A tensor is found to have an orientation different from that of the g and D tensors reflecting the low symmetry of the Ca2+ sites.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Ms V Mangala
Date Deposited: 03 Jun 2011 06:22
Last Modified: 03 Jun 2011 06:22
URI: http://eprints.iisc.ac.in/id/eprint/36158

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