Selvakumar, Natesan and Rao, Subba GSR (1993) Synthesis Based on Cyclohexadienes .11. A A new total synthesis of (±)-norprezizanone. In: Tetrahedron Letters, 34 (48). 7789-7792 .
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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)61567-8
Abstract
Acid catalyzed rearrangement of endo 1-methoxytricyclo[6.2.2.0(3,8)]dodec-2-en-10-ol 8c afforded the ketone 9 which has been transformed into (+/-)-norprezizanone 19 thus completing a formal synthesis of (+/-)-zizaene. A key step in this strategy is a stereospecific 1,4-addition of a methyl group
| Item Type: | Journal Article |
|---|---|
| Publication: | Tetrahedron Letters |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyloaddition; stereospecific 1,4-addition; sesquiterpene synthesis |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 11 Mar 2011 06:38 |
| Last Modified: | 11 Mar 2011 06:38 |
| URI: | http://eprints.iisc.ac.in/id/eprint/35857 |
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