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An unusual anti-markovnikov hydration of alkenes with titanium(III) tetrahydroborates

Kumar, Ravi KS and Baskaran, S and Chandrasekaran, S (1993) An unusual anti-markovnikov hydration of alkenes with titanium(III) tetrahydroborates. In: Tetrahedron Letters, 34 (1). pp. 171-174.

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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)60086-2


Titanium(III) tetrahydroborate formed by the reaction of titanium tetrachloride and benzyltriethylammonium borohydride (1:4) reacts with alkenes in dichloromethane (-20-degrees-C) very readily to yield directly the corresponding alcohols in excel lent yields after a simple aqueous work up.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Ms TV Yashodha
Date Deposited: 31 Jan 2011 07:45
Last Modified: 31 Jan 2011 07:45
URI: http://eprints.iisc.ac.in/id/eprint/35319

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