Synthesis, infrared spectra and thermoanalytical properties of transition metal sulfite hydrazine hydrates

Budkuley, Jayant S and Patil, KC (1990) Synthesis, infrared spectra and thermoanalytical properties of transition metal sulfite hydrazine hydrates. In: Journal of Thermal Analysis, 36 (7-8). pp. 2583-2592.

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Abstract

Transition metal sulfite hydrazine hydrates, MSO3·xN2H4·yH2O whereM=Mn, Fe, Co, Ni and Zn have been prepared and characterized by chemical analysis, infrared spectra, thermoanalytical and combustion studies. The colours,x andy parameters of the complexes varied depending upon the preparation conditions. Thermal decomposition characteristics differ from metal to metal yielding metal oxides at relatively low temperatures.Mittels chemischer Analyse, IR-Spektren, thermoanalytischen und Verbrennungsstudien wurden die Hydrazinhydrate der hergestellten Übergangsmetallsulfite MSO3·xN2H4·yH2O mitM=Mn, Fe, Co, Ni und Zn beschrieben. Farbe sowie die Parameterx undy der Komplexe hängen von den Herstellungsbedingungen ab. Die thermische Zersetzung, bei der bei relativ niedrigen Temperaturen Metalloxide entstehen, ist von Metall zu Metall verschieden.

Item Type:	Journal Article
Publication:	Journal of Thermal Analysis
Publisher:	Springer
Additional Information:	Copyright of this article belongs to Springer.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	11 Jan 2011 07:30
Last Modified:	11 Jan 2011 07:30
URI:	http://eprints.iisc.ac.in/id/eprint/34939

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