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An infrared spectroscopic study of the low-spin-high-spin transition in FexMn1-x(Phen)2(NCS)2: A composition-induced change in the order of the spin-state transition

Varma, Vijay and Fernandes, JR (1990) An infrared spectroscopic study of the low-spin-high-spin transition in FexMn1-x(Phen)2(NCS)2: A composition-induced change in the order of the spin-state transition. In: Chemical Physics Letters, 167 (4). pp. 367-370.

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Official URL: http://dx.doi.org/10.1016/0009-2614(90)87184-S

Abstract

Infrared spectroscopy provides a valuable tool to investigate the spin-state transition in Fe(II) complexes of the type Fe(Phen)2(NCS)2. With progressive substitution of Fe by Mn, the first-order transition changes over to a second-order transition, with a high residual population of the high-spin state even at very low temperatures

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Ms TV Yashodha
Date Deposited: 07 Jan 2011 08:51
Last Modified: 07 Jan 2011 08:51
URI: http://eprints.iisc.ac.in/id/eprint/34883

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