Prabakar, S and Rao, KJ and Rao, CNR (1991) 29Si NMR chemical shifts in silicates. In: Chemical Physics Letters, 183 (3-4). pp. 176-182.
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Official URL: http://dx.doi.org/10.1016/0009-2614(91)80046-Z
Abstract
29Si chemical shifts in a wide variety of silicates in crystalline, glassy and gel states have been related to a parameter, P, which takes into account the electronegativity and the structural description of the silicate units as well as the ionic potential of the modifier cation. The relation, δ(ppm)=28.4 [1−exp(−P)]−110.5, besides having predictive value, satisfactorily accounts for all the available chemical-shifts data on silicates and shows the right kind of limiting behaviour, with δ approaching the Q0 value at large P.
Item Type: | Journal Article |
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Publication: | Chemical Physics Letters |
Publisher: | Elsevier science |
Additional Information: | Copyright of this article belongs to Elsevier science. |
Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
Date Deposited: | 30 Nov 2010 08:58 |
Last Modified: | 30 Nov 2010 08:58 |
URI: | http://eprints.iisc.ac.in/id/eprint/34127 |
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