Miscibility of poly(phenyl acrylate) with acrylonitrile/styrene copolymers

Sankarapandian, M and Kishore, K (1991) Miscibility of poly(phenyl acrylate) with acrylonitrile/styrene copolymers. In: Macromolecules, 24 (11). pp. 3090-3092.

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Abstract

The Blase transition and phase behavior of blends of poly(pheny1 acrylate) with poly(acrylonitri1eco-styrene) was studied by differential scanning calorimetry. It was found that poly(pheny1 acrylate) is miscible with poly(acrylonitri1e-co-styrenes) within a specific range of copolymer composition. The segmental interaction parameters were estimated and found to be positive for all three pairs. The miscibility in thissystem appears to be the consequence of the intramolecular repulsion between styrene and acrylonitrile units.

Item Type:	Journal Article
Publication:	Macromolecules
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 Nov 2010 09:36
Last Modified:	23 Nov 2010 09:36
URI:	http://eprints.iisc.ac.in/id/eprint/33987

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