An efficient construction of a $C_{3}-symmetric$ macrocycle by head to tail cyclotrimerization of an unsymmetrical diene via a sequence of highly regio- and stereoselective metathesis reactions

Srikrishna, A and Dethe, Dattatraya H (2005) An efficient construction of a $C_{3}-symmetric$ macrocycle by head to tail cyclotrimerization of an unsymmetrical diene via a sequence of highly regio- and stereoselective metathesis reactions. In: Tetrahedron Letters, 46 (19). pp. 3381-3383.

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Abstract

A sequence of highly regio- and stereoselective intermolecular metatheses followed by ring-closing metathesis of an1-allyl-3-(3-butenyl)cyclohexanol led to a $C_{3}-symmetric$ head to tailcyclic trimer; a 24-membered macrocycle containing three inward directed hydroxyl groups creating a hydrophilic cavity.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Pergamon-Elsevier Science Ltd
Additional Information:	Copyright fot this article belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	25 May 2005
Last Modified:	19 Sep 2010 04:19
URI:	http://eprints.iisc.ac.in/id/eprint/3247

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