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Chemistry of Tetrathiomolybdate and Tetraselenotungstate: Applications in Carbohydrate Chemistry

Sridhar, Perali Ramu and Saravanan, V and Chandrasekaran, S (2005) Chemistry of Tetrathiomolybdate and Tetraselenotungstate: Applications in Carbohydrate Chemistry. In: Pure and Applied Chemistry, 77 (1). pp. 145-153.

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Official URL: http://iupac.org/publications/pac/77/1/0145/

Abstract

An efficient one pot synthesis of thio and selenolevoglucosans from 1,6-diactivated carbohydrate derivatives has been achieved using benzyltriethylammonium tetrathiomolybdate, $[BnNEt_3]_2MoS_4$, as a sulfur transfer reagent and tetraethylammonium tetraselenotungstate, $[Et_4N]_2WSe_4$, as a selenium transfer reagent, respectively. The methodology has also been extended to the synthesis of 1,5-epithio and 1,5-episeleno pentoses.

Item Type: Journal Article
Publication: Pure and Applied Chemistry
Publisher: International Union of Pure and Applied Chemistry
Additional Information: The copyright for this article belongs to International Union of Pure and Applied Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Apr 2005
Last Modified: 20 Jan 2012 09:17
URI: http://eprints.iisc.ac.in/id/eprint/3021

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