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Potentiometric and spectrophotometric investigations of nickel-triethanolamine complexes

Bhat, GA and Subrahmanya, RS (1972) Potentiometric and spectrophotometric investigations of nickel-triethanolamine complexes. In: Inorganica Chimica Acta, 6 . pp. 403-407.

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Official URL: http://dx.doi.org/10.1016/S0020-1693(00)91827-9

Abstract

A detailed study of nickel-triethanolamine complexes has been made employing potentiometric and spectrophotometric methods. The potentiometric method has been used to investigate the conditions for the formation of both mono- and polynuclear complexes. The formulae and the stability constants of the following complexes have been determined Ni(TEA)2+, Ni(TEA)22+, and Ni2(TEA)24+. Absorption spectra of pure mononuclear complexes have been computed by the combination of potentiometric and spectrophotometric methods. The results are discussed on the basis of ligand field theory. Comparison of the step constants of the nickel-ethanolamines (mono-, di- and tri-) shows a slight chelate effect in these complexes due to coordination through hydroxyl oxygen. In the case of polynuclear complexes it is likely that bridging occurs through hydroxyl oxygen.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Ms TV Yashodha
Date Deposited: 13 Jul 2010 06:16
Last Modified: 19 Sep 2010 06:11
URI: http://eprints.iisc.ac.in/id/eprint/29183

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