Vijayalakshamma, SK and Subrahmanya, RS (1972) Studies in the polarographic and coulometric behaviour of aromatic nitro compounds—III. nitrosobenzene in ethanol, acetone and dioxan. In: Electrochimica Acta, 17 (3). pp. 471-477.
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Abstract
The green nitrosobenzene monomer is reduced polarographically to phenylhydroxylamine in the pH range 4—9. Though this reduction is known to be a two-electron process, coulometry invariably gives a lower value of n because of the reaction of unreacted nitrosobenzene and the phenylhydroxylamine formed. The green monomer is attacked by mercury in acid medium. In alkaline medium, the green monomer undergoes a change that follows first-order kinetics with respect to nitrosobenzene. The rate of the transformation depends on the solvent. It decreases in the order acetone > ethanol > dioxan.
Item Type: | Journal Article |
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Publication: | Electrochimica Acta |
Publisher: | Elsevier Science |
Additional Information: | Copyright of this article belongs to Elsevier Science. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 13 Jul 2010 06:00 |
Last Modified: | 19 Sep 2010 06:10 |
URI: | http://eprints.iisc.ac.in/id/eprint/29142 |
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