Nickel(II) complexes of 1-benzyl-2-phenylbenzimidazole

Bose, KS and Patel, CC (1971) Nickel(II) complexes of 1-benzyl-2-phenylbenzimidazole. In: Journal of Inorganic and Nuclear Chemistry, 33 (3). pp. 755-759.

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Abstract

Nickel(II) complexes of 1-benzyl-2-phenylbenzimidazole (BPBI) of the general formula [Ni(BPBI)2X2](X=Cl-, Br-, NCS- or NO3-) have been prepared and their magnetic moments, i.r. and electronic spectra studied. [Ni(BPBI)2Cl2] has a pseudotetrahedral structure while [Ni(BPBI)2 Br2] exists as square planar and speudotetrahedral isomers. [Ni(BPBI)2I2] and [NI(BPBI)2(NCS)2] have square planar stereochemistry. The nitrato complex [Ni(BPBI)2(NO)3)2] exists in two different octahedral modifications in the solid state.

Item Type:	Journal Article
Publication:	Journal of Inorganic and Nuclear Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 Jun 2010 05:18
Last Modified:	19 Sep 2010 06:09
URI:	http://eprints.iisc.ac.in/id/eprint/28575

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