Banerjee, DK and Bagavant, G (1960) Isomerisations of substituted β-keto-esters - Part II. Isomerisation of ethyl 1-ethoxycarbonyl 2oxocyclopentyl acetate into 2, 3-diethoxycarbonylcyclohexanone. In: Proceedings of the Indian Academy of Sciences - Section A, 52 (4). pp. 165-172.
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Abstract
A mechanism for the isomerisation of ethyl 1-ethoxycarbonyl-2-oxocyclopentylacetate (I) into a cyclohexane β-keto-ester as proceeding through an intermediate bicyclic /gb-diketone (VII) has been considered as an alternative mechanism to one earlier suggested.1 The determination of the structure of the isomerised β-keto-ester as 2, 3-diethoxycarbonylcyclohexanone (V) has provided support for the earlier mechanism.
Item Type: | Journal Article |
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Publication: | Proceedings of the Indian Academy of Sciences - Section A |
Publisher: | Indian Academy of Sciences |
Additional Information: | Copyright of this article belongs to Indian Academy of Sciences. |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 23 Jun 2010 05:36 |
Last Modified: | 19 Sep 2010 06:09 |
URI: | http://eprints.iisc.ac.in/id/eprint/28527 |
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