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Dimethyl sulphoxide complexes of lanthanide and yttrium nitrates

Ramalingam, SK and Soundararajan, S (1967) Dimethyl sulphoxide complexes of lanthanide and yttrium nitrates. In: Journal of Inorganic and Nuclear Chemistry, 29 (7). 1763 -1768.

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Official URL: http://dx.doi.org/10.1016/0022-1902(67)80220-3

Abstract

Dimethyl sulphoxide complexes of lanthanide and yttrium nitrates of the general formula M(DMSO)n(NO3)3 where M = La, Ce, Pr, Nd, Sm or Gd; n = 4 and M = Y, Ho or Yb; n = 3 have been isolated and characterized. The i.r. data besides excluding the presence of D3h nitrate, reveal co-ordination through the oxygen atom of the dimethyl sulphoxide. The complexes are monomeric in acetonitrile. Molecular conductance data in acetone, acetonitrile, dimethyl formamide and dimethyl sulphoxide suggest a co-ordination number of eight for the lighter lanthanides and seven for yttrium and the heavier lanthanides.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Ms TV Yashodha
Date Deposited: 13 May 2010 06:26
Last Modified: 19 Sep 2010 06:06
URI: http://eprints.iisc.ac.in/id/eprint/27815

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