In Situ Cryocrystallization of Diphenyl Ether: C-H...\pi Mediated Polymorphic Forms

Choudhury, Angshuman R and Islam, Kabirul and Kirchner, Michael T and Mehta, Goverdhan and Row, Tayur Guru N (2004) In Situ Cryocrystallization of Diphenyl Ether: C-H...\pi Mediated Polymorphic Forms. In: Journal of the American Chemical Society, 126 (39). pp. 12274-12275.

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Abstract

Polymorphism in diphenyl ether has been identified during in situ crystallization via single-crystal X-ray diffraction. Only weak inter- and intramolecular C-H...\pi interactions control the packing of the molecules in both crystal forms monoclinic centrosymmetric $(P2_1/n)$ in form I and orthorhombic noncentrosymmetric $(P2_12_12_1)$ in form II.

Item Type:	Journal Article
Publication:	Journal of the American Chemical Society
Publisher:	American Chemical Society
Additional Information:	Copyright for this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit Division of Chemical Sciences > Organic Chemistry
Date Deposited:	14 Feb 2007
Last Modified:	19 Jan 2012 04:51
URI:	http://eprints.iisc.ac.in/id/eprint/2648

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