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Mechanics of Deformation under Traction and Friction of a Micrometric Monolithic MoS2 Particle in Comparison with those of an Agglomerate of Nanometric MoS2 Particles

Sahoo, Rashmi R and Math, Souvik and Biswas, SK (2010) Mechanics of Deformation under Traction and Friction of a Micrometric Monolithic MoS2 Particle in Comparison with those of an Agglomerate of Nanometric MoS2 Particles. In: Tribology Letters, 37 (2). pp. 239-249.

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Abstract

Tribology of small inorganic nanoparticles in suspension in a liquid lubricant is often impaired because these particles agglomerate even when organic dispersants are used. In this paper we use lateral force microscopy to study the deformation mechanism and dissipation under traction of two extreme configurations (1) a large MoS2 particle (similar to 20 mu m width) of about 1 mu m height and (2) an agglomerate (similar to 20 mu m width), constituting 50 nm MoS2 crystallites, of about 1 mu m height. The agglomerate records a friction coefficient which is about 5-7 times that of monolithic particle. The paper examines the mechanisms of material removal for both the particles using continuum modeling and microscopy and infers that while the agglomerate response to traction can be accounted for by the bulk mechanical properties of the material, intralayer and interlayer basal planar slips determine the friction and wear of monolithic particles. The results provide a rationale for selection of layered particles, for suspension in liquid lubricants.

Item Type: Journal Article
Publication: Tribology Letters
Publisher: Springer
Additional Information: Copyright of this article belongs to Springer.
Keywords: Molybdenum disulfide; Atomic force microscopy (AFM); Friction; Solid lubricant additives
Department/Centre: Division of Mechanical Sciences > Mechanical Engineering
Date Deposited: 24 Feb 2010 09:03
Last Modified: 19 Sep 2010 05:55
URI: http://eprints.iisc.ac.in/id/eprint/25777

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