N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol

Becker, Edwin D and Tucker, Edwin E and Rao, CNR (1977) N. m. r. and infrared spectroscopic studies of hydrogen bonding in hindered alcohols. An instance of a true hydrogen bonded dimer in an alcohol. In: Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 73 . pp. 438-442.

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Abstract

Hydrogen bonding in the highly hindered alcohol 2,4-dimethyl-3-ethyl-3-pentanol has been studied by proton n.m.r. and infrared spectroscopy. This alcohol associates to form a dimer but no higher hydrogen bonded species; hence the monomer–dimer equilibrium can be studied without interference from competing processes. Spectral and thermodynamic properties for the hydrogen bonding are reported.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Publisher:	Royal Society London
Additional Information:	Copyright of this article belongs to Royal Society London.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	29 Jan 2010 12:03
Last Modified:	19 Sep 2010 05:51
URI:	http://eprints.iisc.ac.in/id/eprint/24629

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