Chandra, AK (1979) The perturbational treatment of the process of hydrogen abstraction by ketones. In: Journal of Photochemistry, 11 (5). pp. 347-360.
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Abstract
The change in energy during hydrogen abstraction by ketones is estimated for different electronic states as a function of the intermolecular orbital overlap employing perturbation theory. The results suggest that ketones preferentially undergo the in-plane reaction and abstract a hydrogen atom in their triplet nπ* state. For ketones where the triplet ππ* state lies below the triplet nπ* state, hydrogen abstraction can take place in the ππ* state owing to the crossing of the zero order reaction surfaces of the nπ* and ππ* states.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Photochemistry |
| Publisher: | Elsevier Science |
| Additional Information: | Copy right of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 05 Jan 2010 06:04 |
| Last Modified: | 19 Sep 2010 05:50 |
| URI: | http://eprints.iisc.ac.in/id/eprint/24343 |
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