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Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes

Sudha, BP and Dixit, NS and Patel, CC (1977) Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes. In: Proceedings of the Indian Academy of Science Section A, 86 (5). pp. 471-477.

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Preparation and structural characterization of palladium (II) complexes of ligands III-V and copper (II) complexes of III are reported. The elemental analyses of the complexes show that the metal: ligand ratio is 1 : 2. The electrical conductance in acetone shows the non-electrolytic nature of the complexes. The diamagnetic character suggests a gross square-planar geometry for the palladium (II) complexes. Copper (II) complexes are paramagnetic with/~eff.~l'90 B.M. Spectral data suggest that in all the complexes the ligand coordinates to the metal (II) symmetrically through isonitroso-nitrogen and imine-nitrogen, forming a ¡ membered chelate ring. Amine-exchange reactions of the complexes are discussed and compared on the basis of their structures.

Item Type: Journal Article
Additional Information: copyright of this article belongs to Indian Academy of Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Paramesha S
Date Deposited: 15 Jan 2010 06:33
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ac.in/id/eprint/24009

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