Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes

Sudha, BP and Dixit, NS and Patel, CC (1977) Coordination properties of vic-isonitrosoimines in their copper (II) and palladium (II) complexes. In: Proceedings of the Indian Academy of Science Section A, 86 (5). pp. 471-477.

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Abstract

Preparation and structural characterization of palladium (II) complexes of ligands III-V and copper (II) complexes of III are reported. The elemental analyses of the complexes show that the metal: ligand ratio is 1 : 2. The electrical conductance in acetone shows the non-electrolytic nature of the complexes. The diamagnetic character suggests a gross square-planar geometry for the palladium (II) complexes. Copper (II) complexes are paramagnetic with/~eff.~l'90 B.M. Spectral data suggest that in all the complexes the ligand coordinates to the metal (II) symmetrically through isonitroso-nitrogen and imine-nitrogen, forming a ¡ membered chelate ring. Amine-exchange reactions of the complexes are discussed and compared on the basis of their structures.

Item Type:	Journal Article
Publication:	Proceedings of the Indian Academy of Science Section A
Publisher:	Springer India, in co-publication with Indian Academy of Sciences
Additional Information:	copyright of this article belongs to Indian Academy of Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	15 Jan 2010 06:33
Last Modified:	19 Sep 2010 05:48
URI:	http://eprints.iisc.ac.in/id/eprint/24009

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