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Photodecomposition of ammonium oxalate

Nair, MN Radhakrishnan and Verneker, VR Pai (1976) Photodecomposition of ammonium oxalate. In: Journal of Physical Chemistry, 80 (23). pp. 2552-2555.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100564a005

Abstract

The ultraviolet induced photodecomposition of ammonium oxalate has been studied. The rate-time plots show an initial deceleration region which leads to a final constant value. The intensity dependence of the photorate can be represented by an equation of the type R = AI + BP. The photolysis was found to be sensitized by precompression and desensitized by ageing. Similarly the photolytic rate of ammonium oxalate crystallized from solutions containing phosphate ion and chloride ion impurity showed a sensitization and desensitization, respectively.

Item Type: Journal Article
Publication: Journal of Physical Chemistry
Publisher: ACS Publications
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 11 Dec 2009 07:05
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ac.in/id/eprint/24005

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