The heat capacity of liquid carbon disulfide + acetonitrile, especially near the upper critical solution temperature

Govindarajan, K and Viswanathan, B and Gopal, ESR (1973) The heat capacity of liquid carbon disulfide + acetonitrile, especially near the upper critical solution temperature. In: The Journal of Chemical Thermodynamics, 5 (1). pp. 73-81.

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Abstract

The heat capacity Cp of the binary liquid system CS2 + CH3CN has been studied. This system has an upper critical solution temperature To ≈ 323.4 K and a critical mole fraction of CS2xo ≈ 0.5920. Measurements were made both for mixtures close to and far away from the critical region. The heat capacity of the mixture with x = xo exhibits a symmetric logarithmic anomaly around Tc, which is apparently preserved even for compositions in the immediate vicinity of xc. For compositions far away from xc, only a normal rise in Cp over the covered temperature range is observed.

Item Type:	Journal Article
Publication:	The Journal of Chemical Thermodynamics
Publisher:	Elsevier Science
Additional Information:	Copy right of this article belongs to Elsevier Science.
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	09 Jan 2010 09:18
Last Modified:	19 Sep 2010 05:48
URI:	http://eprints.iisc.ac.in/id/eprint/23943

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