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Critical point phenomena in the electrical resistivity of binary liquid systems: Cs2 + CH3CN and CS2 + CH3NO2

Gopal, ESR and Lele, MV and Ramakrishnan, J and Sekhar, P Chandra and Subramanyam, SV (1976) Critical point phenomena in the electrical resistivity of binary liquid systems: Cs2 + CH3CN and CS2 + CH3NO2. In: Pramana, 7 (4). pp. 766-776.

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Abstract

Electrical resistance measurements are reported on the binary liquid mixtures CS2 + CH3CN and CS2 + CH3NO2 with special reference to the critical region. Impurity conduction seems to be the dominant mechanism for charge transport. For the liquid mixture filled at the critical composition, the resistance of the system aboveT c follows the relationR=R c−A(T−T c) b withb=0·6±0·1. BelowT c the conductivities of the two phases obey a relation σ2−σ1=B(T c−T)β with β=0·34±0·02, the exponent of the transport coefficient being the same as the exponent of the order parameter, an equilibrium property.

Item Type: Journal Article
Publication: Pramana
Publisher: Springer India, in co-publication with Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Springer.
Keywords: Critical phenemena - binary systems - critical indices - transport properties resistivity
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 11 Dec 2009 09:27
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ac.in/id/eprint/23939

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