Patil, KC and Ramanath, M and Ramanath, M (1981) Thermal decomposition and combustion of ammine: AP pellets. In: Combustion and Flame, 42 (3). pp. 321-326.
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Thermal decomposition and combustion of lithium perchlorate ammine:ammonium perchlorate (LPA:AP) and magnesium perchlorate ammine:ammonium perchlorate (MPA:AP) pellets have been studied using DTA, TG, and strand burner techniques. The DTA results of the ammine:AP pellets show that the addition of ammines lowers the ignition temperature of AP. However, isothermal TG of the ammine:AP pellets show that in the case of LPA:AP pellets the extent of decomposition increases with the increase in the concentration of LPA; whereas in the case of MPA:AP pellets the extent of decomposition decreases with the increase in the concentration of MPA. Similarly, LPA:AP pellets show higher burning rates compared to AP pellets. On the other hand, MPA:AP pellets show lower burning rates compared to AP pellets. Increasing the concentration of MPA in MPA:AP pellets completely suppresses the combustion. These results are explained on the basis of the thermal characteristics of the additives and their decomposition products.
| Item Type: | Journal Article |
|---|---|
| Publication: | Combustion and Flame |
| Publisher: | Elsevier Science |
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 12 Jan 2010 10:57 |
| Last Modified: | 12 Jan 2010 10:57 |
| URI: | http://eprints.iisc.ac.in/id/eprint/23383 |
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