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Synthesis and Characterisation of Metal Hydrazine Nitrate, Azide and Perchlorate Complexes

Patil, KC and Nesamani, C and Verneker, VR Pai (1982) Synthesis and Characterisation of Metal Hydrazine Nitrate, Azide and Perchlorate Complexes. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 12 (4). pp. 383-395.

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Metal hydrazine nitrate complexes of the type M(N2H4)Nn (NO3)2 where M = Mg, n = 2; M = Mn, Fe, Co, Ni, Zn and Cd and n = 3; metal dihydrazine azide complexes of the type M(N2H4)2 (N3)2 where M = Mg, Co, Ni and Zn; and Mg(N2H4)2 (C1O4)2 have been prepared by dissolving the respective metal powders in the solution of corresponding ammonium salts (NO3, N3 and C1O4) in hydrazine hydrate. These hydrazine complexes were also prepared by the conventional method involving the addition of alcoholic hydrazine hydrate to the aqueous solution of metal salts. The hydrazine complexes have been characterised by chemical analysis, infrared spectra and differential thermal analysis (DTA). Impact sensitivities of hydrazine complexes were determined by the drop weight method. The reactivity of these hydrazine complexes does not change with the method of preparation.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Mahesh Y
Date Deposited: 22 Dec 2009 08:16
Last Modified: 22 Dec 2009 08:16
URI: http://eprints.iisc.ac.in/id/eprint/23189

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