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Tautomeric forms of hydroxycyclotriphosphazatrienes; X-ray crystal structure of N3P3Ph2(OMe)3OH

Dhathathreyan, KS and Krishnamurthy, SS and Murthy, AR Vasudeva and Cameron, T Stanley and Chan, Christine and Shaw, Robert A and Woods, Michael (1980) Tautomeric forms of hydroxycyclotriphosphazatrienes; X-ray crystal structure of N3P3Ph2(OMe)3OH. In: Journal of the Chemical Society, Chemical Communications . pp. 231-233.

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The prefered tautomer(s) of hydroxycyclotriphosphazatrienes and prototropic exchange in solution have been established by 31P n.m.r. spectroscopy, thus confirming predictions deduced from basicity calculations; the X-ray structure of N3P3Ph2(OMe)3OH shows that it exists as the hydrogen-bonded dimer of the oxophosphazadiene tautomer in which a proton is adjacent to the PPh2 group.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry, 2009
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: pallab
Date Deposited: 05 Feb 2010 06:26
Last Modified: 19 Sep 2010 05:43
URI: http://eprints.iisc.ac.in/id/eprint/22923

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