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Steric Aspects Of The Oxidation Of Thioketones By Singlet Oxygen

Ramnath, Narayan and Rao, Vaidhya Jayathertha and Ramesh, Varadaraj and Ramamurthy, Vaidhyanathan (1982) Steric Aspects Of The Oxidation Of Thioketones By Singlet Oxygen. In: Chemistry Letters, 11 (1). pp. 89-92.

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Abstract

Singlet oxygen oxidation of dialkyl thioketones yields the corresponding ketones and in some cases sulfoxides in varying amounts. Steric considerations on the reactive zwitterionic/diradical intermediates have been invoked to rationalise the product distribution.

Item Type: Journal Article
Publication: Chemistry Letters
Publisher: Chemical Society of Japan
Additional Information: Copyright of this article belongs to Chemical Society of Japan.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 31 Dec 2009 06:52
Last Modified: 19 Sep 2010 05:43
URI: http://eprints.iisc.ac.in/id/eprint/22686

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