Thermal properties of 3BaO-3TiO(2)-B2O3 glasses

Vaish, Rahul and Varma, KBR (2009) Thermal properties of 3BaO-3TiO(2)-B2O3 glasses. In: Philosophical Magazine, 89 (19). pp. 1555-1564.

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Abstract

Transparent glasses in the system 3BaO-3TiO2-B2O3 (BTBO) were fabricated via the conventional melt-quenching technique. The as-quenched samples were confirmed to be non-crystalline by differential thermal analysis (DTA). Thermal parameters were evaluated using non-isothermal DTA experiments. The Kauzmann temperature was found to be 759 K based on heating-rate-dependent glass transition and crystallization temperatures. A theoretical relation for the temperature-dependent viscosity is proposed for these glasses and glass-ceramics.

Item Type:	Journal Article
Publication:	Philosophical Magazine
Publisher:	Taylor and Francis Group
Additional Information:	Copyright of this article belongs to Taylor and Francis Group.
Keywords:	calorimetry;crystallization;glass;glass ceramics;glass transition;kinetics.
Department/Centre:	Division of Chemical Sciences > Materials Research Centre
Date Deposited:	22 Dec 2009 07:29
Last Modified:	19 Sep 2010 05:41
URI:	http://eprints.iisc.ac.in/id/eprint/22438

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