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NMR Spectroscopic and X-Ray Structural Studies of Two Diazadiphosphetidines

Kumaravel, SS and Sudhakara Rao, SP and Krishnamurthy, SS and Vincent, BN and Cameron, TS (1987) NMR Spectroscopic and X-Ray Structural Studies of Two Diazadiphosphetidines. In: Phosphorus, Sulfur, and Silicon and the Related Elements, 30 (3-4). 697 -697.

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The crystal structures of the two diazadiphosphetidines, [PhNP(OCH2CF3)]2 (1) and [MeNP(NMe2)(O2C6H4)]2 (2) have been determined. The trifluoroethoxy groups in (1) have a trans orientation. The phosphorus chemical shift for (1) is at 189.8 δ. On standing in solution, (1) transforms slowly (∼ 10 days) and almost completely into its 'high-field' (cis) isomer (142.2δ).

Item Type: Journal Article
Additional Information: Copy right of this article belongs to Taylor and Francis Group.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Mrs Swathi
Date Deposited: 15 Jan 2010 06:32
Last Modified: 15 Jan 2010 06:32
URI: http://eprints.iisc.ac.in/id/eprint/21364

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