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Total synthesis of (G)-herbertenediol

Srikrishna, A and Satyanarayana, G (2006) Total synthesis of (G)-herbertenediol. In: Tetrahedron, 62 (12). pp. 2892-2900.

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A formal total synthesis of the sesquiterpene (+/-)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsavier.
Keywords: Herbertanes;Mastigophorenes;RCM reaction;Claisen rearrangement;Vicinal quaternary carbon atoms.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: NG Nishad
Date Deposited: 13 Apr 2009 06:41
Last Modified: 19 Sep 2010 05:02
URI: http://eprints.iisc.ac.in/id/eprint/18475

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