Aqueous organotin chemistry: Tin hydride mediated dehalogenation of organohalides and a novel organotin mediated nucleophilic substitution on 2-iodobenzoates in water

Sarma, Koushik Das and Maitra, Uday (1998) Aqueous organotin chemistry: Tin hydride mediated dehalogenation of organohalides and a novel organotin mediated nucleophilic substitution on 2-iodobenzoates in water. In: Tetrahedron, 54 (19). pp. 4965-4976.

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Abstract

This paper describes the dehalogenation of water soluble and water insoluble organohalides in water by tri-n-butyltin hydride (TBTH), preformed TBTH and triphenyltin hydride (TPTH) in water. TBTH in the presence of a radical trap, and Ph4Sn were also found to effect nucleophilic substitution of 2-iodobenzoates in the presence of various nucleophiles.

Item Type:	Journal Article
Publication:	Tetrahedron
Publisher:	Elsevier Science
Additional Information:	Copyright of this article Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	05 Mar 2009 06:03
Last Modified:	02 May 2011 07:06
URI:	http://eprints.iisc.ac.in/id/eprint/18063

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