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A highly flexible route to tricyclo[4.3.1.03.7]-, and tricyclo[4.3.0.04,10]decanes A short synthesis of pupukean-2-one

Biju, John P and Rao, Subba GSR (1999) A highly flexible route to tricyclo[4.3.1.03.7]-, and tricyclo[4.3.0.04,10]decanes A short synthesis of pupukean-2-one. In: Tetrahedron Letters, 40 (1). pp. 181-184.

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Abstract

An efficient strategy for the construction of tricyclo[4.3.1.0(3,7)]-, and tricyclo[4.3.0.0(4,10)]decanes is described which involves a novel one-pot tandem acid-catalyzed rearrangement followed by an ene cyclization as key step and is exemplified by the total synthesis of pupukean-2-one 3. (C) 1998 Elsevier Science Ltd. All rights reserved.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 12 Aug 2009 08:37
Last Modified: 19 Sep 2010 04:58
URI: http://eprints.iisc.ac.in/id/eprint/17803

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