5'-O-(Toluenesuifonyl)adenosine

Prahadeeswaran, D and Seshadri, TP (1999) 5'-O-(Toluenesuifonyl)adenosine. In: Acta Crystallographica Section C, 55 (3). pp. 389-391.

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Abstract

The title compound, C17H19N5O6S, crystallizes from a water-acetone solution. The adenine base is in an anti conformation, with a glycosyl torsion angle of - 166.5 (4)degrees. The ribose sugar adopts an envelope conformation (E-3). The toluenesulfonyl moiety is nearly perpendicular to the base. Both Watson-Crick and Hoogsteen sites, N1 and N6, and N6 and N7, of the adenine base are involved in a pair of hydrogen bonds, forming an A.A.A triplet pattern in the crystal lattice.

Item Type:	Journal Article
Publication:	Acta Crystallographica Section C
Publisher:	Intenational Union of Crystallography
Additional Information:	Copyright of this article belongs to International Union of Crystallography.
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	26 Dec 2008 10:43
Last Modified:	19 Sep 2010 04:57
URI:	http://eprints.iisc.ac.in/id/eprint/17613

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