Garg, Rohini and Senyshyn, Anatoliy and Boysen, Hans and Ranjan, Rajeev (2008) Structure and phase transition of Na0.5La0.5TiO3. In: Journal of Physics:Condensed Matter, 20 (50). pp. 505215-1.
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Abstract
A temperature dependent neutron powder diffraction study was carried out on Na0.5La0.5TiO3 (NLT) from 298 K up to 1373 K. Rietveld analysis using high resolution x-ray and neutron powder diffraction data confirmed the rhombohedral structure (space group R\bar {3}c ) of this compound. The rhombohedral phase transforms to cubic (Pm\bar {3}m ) above 873 K. The temperature variation of the tilt angle, a continuous change of the specific volume across the transition, and the strain analysis suggest a second order nature of the cubic–rhombohedral phase transition, which is in conformity with the group theoretical prediction based on symmetry considerations.
Item Type: | Journal Article |
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Publication: | Journal of Physics:Condensed Matter |
Publisher: | Institute of Physics |
Additional Information: | Copyright of this article belongs to Institute of Physics. |
Department/Centre: | Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy) |
Date Deposited: | 24 Jul 2009 08:49 |
Last Modified: | 19 Sep 2010 04:57 |
URI: | http://eprints.iisc.ac.in/id/eprint/17476 |
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