Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus $\mathit{Helicobasidium{\:}mompa}$. Structure revision of HM-2

Srikrishna, A and Ravikumar, PC (2005) Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus $\mathit{Helicobasidium{\:}mompa}$. Structure revision of HM-2. In: Tetrahedron Letters, 46 (36). pp. 6105-6109.

PDF sdarticle.pdf - Published Version Restricted to Registered users only Download (138kB) | Request a copy

Abstract

The structure assigned to the sesquiterpene HM-2 was found to be incorrect by total synthesis. A ring-closing metathesis based strategy was developed for the total synthesis of the aromatic sesquiterpene HM-1, which on functional group transformation established the structure of HM-2 as 23, a cuparene derivative. (c) 2005 Elsevier Ltd. All rights reserved.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier
Additional Information:	Copyright of this article belongs to Elsevier.
Keywords:	HM-1 to 4;Structure revision;Herbertenoids;Cuparenoids;RCM.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	04 Feb 2010 10:51
Last Modified:	19 Sep 2010 04:56
URI:	http://eprints.iisc.ac.in/id/eprint/17407

Actions (login required)

View Item