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Amine-templated metal squarates

Dan, Meenakshi and Sivashankar, K and Cheetham, AK and Rao, CNR (2003) Amine-templated metal squarates. In: Journal of Solid State Chemistry, 174 (1). pp. 60-68.

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Two layered amine-templated cobalt squarates, $[C_{6}N_{2}H_{14}]2[Co_{2}(C_{4}O_{4})3(H_{2}O)4]$, I, and$ [C_{3}N_{2}H_{5}]2[Co_{2}(C_{4}O_{4})3(H_{2}O)4], $II, have been prepared under hydrothermal conditions. Both I and II contain chains formed by dimers comprising two cobalt atoms bound to the squarate units, the chains being connected through hydrogen bond interactions. An amine-templated cobalt squarate of the formula$ [C_{4}N_{2}H_{12}][Co(C_{4}O_{4})2(H_{2}O)4][H_{2}O]2,$ III, as well as its Ni, Zn and Cd analogues have been prepared by room temperature reactions. III has a layered architecture wherein the cobalt-squarate monomers are linked by the amine molecules. Co and Zn analogues of$ [Ni(C_{4}O_{4})(H_{2}O)2(C_{3}N_{2}H_{4})]$ with ligating imidazole units have also been prepared and characterized.

Item Type: Journal Article
Publication: Journal of Solid State Chemistry
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science
Keywords: Organic Framework; Oxalates; Spectra; Crystal; Nickel;Ni
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 03 Dec 2008 08:50
Last Modified: 19 Sep 2010 04:52
URI: http://eprints.iisc.ac.in/id/eprint/16581

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