Mahesh, GV and Ravindranathan, P and Patil, KC (1986) Preparation, characterization and thermal analysis of rare earth and uranyl hydrazinecarboxylate derivatives. In: Journal of Chemical Sciences, 97 (2). pp. 117-123.
Full text not available from this repository. (Request a copy)Abstract
$Ln(N_2H_3CO_2)3.3H_2O$ (Ln = Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Y) and $UO_2(N_2H_3CO_2)2.N_2H_4.H_2O$ were prepared and characterized by chemical analysis. and IR spectra. Simultaneous thermogravimetry (TG)-differential TG-DTA of Ln$(N_2H_3CO_2)3.3H_2O$ show that the thermal decompositions occur through carbonate and oxycarbonate intermediates to the respective oxides. The oxide formation temperature are lower than the corresponding oxalates and acetates. $UO_2(N_2H_3CO_2)2.N_2H_4.H_2O$ decomposes to U3O8 as the final product of decompositions.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Chemical Sciences |
| Publisher: | Indian Academy of Sciences |
| Additional Information: | Copyright for this article beongs to Indian Academy of Sciences. |
| Keywords: | Preparation;characterization;thermal analysis;rare earth;uranyl;hydrazinecarboxylate;derivatives. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 29 Jul 2008 |
| Last Modified: | 27 Aug 2008 13:39 |
| URI: | http://eprints.iisc.ac.in/id/eprint/15327 |
Actions (login required)
 |
View Item |
