Many-Body Effects in Electrochemisorption Part II. Operator Averages and MF-HF Limits

Mishra, AK and Rangarajan, SK (1987) Many-Body Effects in Electrochemisorption Part II. Operator Averages and MF-HF Limits. In: Journal of Electroanalytical Chemistry, 229 (1-2). pp. 67-86.

PDF full.pdf Restricted to Registered users only Download (1MB) | Request a copy

Abstract

The formalism developed in Part I, when approximated, leads to certain operator averages to be evaluated. Simple schemes for obtaining such averages - the mean field correlation approach (MFCA) and the correlation approach (CA) - are outlined. As a zeroth approximation, the Hartree-Fock/mean field case is deduced and compared with the results of Schmickler et al. Some relevant results of the many-body theory are recalled in the Appendix.

Item Type:	Journal Article
Publication:	Journal of Electroanalytical Chemistry
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 Jun 2008
Last Modified:	19 Sep 2010 04:45
URI:	http://eprints.iisc.ac.in/id/eprint/14265

Actions (login required)

View Item